The reflection of color

Color internal reflection is an optical phenomenon that occurs when a ray of light strikes a medium boundary at an angle larger than a particular critical angle with respect to the normal to the surface. If the refractive index is lower on the other side of the boundary, no light can pass through and all of the light is reflected. The critical angle is the angle of incidence above which the total internal reflection occurs.

When light crosses a boundary between materials with different refractive indices, the light beam will be partially refracted at the boundary surface, and partially reflected. However, if the angle of incidence is greater (i.e. the ray is closer to being parallel to the boundary) than the critical angle – the angle of incidence at which light is refracted such that it travels along the boundary – then the light will stop crossing the boundary altogether and instead be totally reflected back internally. This can only occur where light travels from a medium with a higher [n1=higher refractive index] to one with a lower refractive index[n2=lower refractive index]. For example, it will occur when passing from glass to air, but not when passing from air to glass.

One can demonstrate total internal reflection by filling a sink or bath with water, taking a glass tumbler, and placing it upside-down over the plug hole (with the tumbler completely filled with water). While water remains both in the upturned tumbler and in the sink surrounding it, the plug hole and plug are visible since the angle of refraction between glass and water is not greater than the critical angle. If the drain is opened and the tumbler is kept in position over the hole, the water in the tumbler drains out leaving the glass filled with air, and this then acts as the plug. Viewing this from above, the tumbler now appears mirrored because light reflects off the air/glass interface.

Another very common example of total internal reflection is a critically cut diamond. This is what gives it maximum sparkle.